(c)
(i) bond enthalpies are average values/differ(slightly) from one compound to another (depending on the neighbouring atoms) / methanol is liquid not gas in the reaction.
(ii) notall heat produced transferred to water / heat lostto surroundings/environment / OWTTE / incomplete combustion (of methanol) / water forms as H2O(l) instead of H2O(g).
Donot allow just “heat lost”.