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제목 [Kelda Park] AP Chemistry from Samuel Roh
Lesson 1. Atomic structure(1) and (2) 1
작성자 shi*** 등록일 2019-10-08 오후 10:32:56

안녕하세요.

1. P.E는 I.E와 같아서 만약 potential energy로 electron을 eject시키면

electron의 기존 potential energy가 add 않된다고 하셨는데 맞나요?


2. 또한 energy shell는 discrete 정해져 있다고 말씀하셨는데, 

그 뜻은 모든 element의 첫번째 shell에 각각 electron이 두번째 shell로 올라간다면 필요한 energy가 다 같다는 뜻이 아니죠? 

그저 energy shell가 나누어진 데로만 energy가 정해졌다는 것이죠? 

모든 element가 같은 양의 energy를 release한다는 뜻은 X?

Because of element have different ionization energy?


3. Lecture (2)에 Ionization energy를 설명하셨는데 그저 atomic radius와 반대이기 때문에 decrease한다 or increase한다 

이런 식으로 그냥 알아도 되나요? 

아니면 atomic radius 설명하신데로 shell이 증가하면 shielding effect가 증가하여 

effective nuclear charge가 감소하기 때문에 I.E는 감소한다는 식으로 알아야 되나요?  


2019-10-12 오후 12:49:27

Hi! This is Kelda writing. 

I'm really sorry for the late reply. I was away from Korea, and their internet connection was bad. 

So I'm now answering just right after I get back to Korea. Sorry for that!!

 

1. P.E 와 I.E 가 같은 말은 아니지만 같은 의미란 뜻입니다 

electron 이 eject 되기 위해서 promoted to the highest energy level (of which n = infinity), then electron will have a higher P.E by that much gap. 

 

Potential energy is dependant for each gap between electronic shells. 

 

2. The gaps between shells are all different. It doesn't have to be same for each gap. Actually, there is some formula for that calculation (which is called Rydberg equation), but it is removed from AP exam criteria. 

그저 energy shell가 나누어진 데로만 energy가 정해졌다는 것이죠?  --> So what you wrote is correct, their gaps are different, but determined for each element. And shells are not continuous, they are all separated. Their gaps will be affected by the number of protons and the number of electrons and their interaction (attraction and repulsion as well). 

 

3. You should clearly know that ionization energy has a different tendency to the atomic radius. But it's not enough. You should be able to explain it in terms of effective nuclear charges or shielidng effect or Coulombic forces. It will come up in the FRQ section. 

 

 

I hope it helps!

Thank you! 

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